Über pleistozäne Gebirgsbildung und rezente Krustenbewegungen in der Niederrheinischen Bucht     

Hans Wilhelm Quitzow  Otto Vahlensieck 《International Journal of Earth Sciences》1955,43(1):56-67

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The geochemical cycle of boron: Constraints from boron isotope partitioning experiments between mica and fluid   总被引：8，自引：0，他引：8  

Bernd Wunder  Anette Meixner  Rolf L. Romer  Richard Wirth  Wilhelm Heinrich 《Lithos》2005,84(3-4):206-216

The fractionation of boron isotopes between synthetic boromuscovite and fluid was experimentally determined at 3.0 GPa/500 °C and 3.0 GPa/700 °C. For near-neutral fluids Δ¹¹B_(mica-fluid) = δ¹¹B_(mica) − δ¹¹B_(fluid) is − 10.9 ± 1.3‰ at 500 °C, and − 6.5 ± 0.4‰ at 700 °C. This supports earlier assumptions that the main fractionation effect is due to the change from trigonal coordination of boron in neutral fluids to tetrahedrally coordinated boron in micas, clays and melts. The T-dependence of this effect is approximated by the equation Δ¹¹B_{(mica,clay,melt–neutral fluid)} = − 10.69 · (1000/T [K]) + 3.88; R² = 0.992, valid from 25 °C for fluid–clay up to about 1000 °C for fluid–silicate melt. Experiments at 0.4 GPa that used strongly basic fluids produced significantly lower fractionations with Δ¹¹B_{(mica–fluid)} of − 7.4 ± 1.0‰ at 400 °C, and − 4.8 ± 1.0‰ at 500 °C, showing the reduced fractionation effect when large amounts of boron in basic fluids are tetrahedrally coordinated. Field studies have shown that boron concentrations and ¹¹B/¹⁰B-ratios in volcanic arcs systematically decrease across the arc with increasing distance from the trench, thus reflecting the thermal structure of the subducting slab. Our experiments show that the boron isotopic signature in volcanic arcs probably results from continuous dehydration of micas along a distinct P–T range. Continuous slab dehydration and boron transport via fluid into the mantle wedge is responsible for the boron isotopic signature in volcanic arcs.  相似文献   

Ultraviolet Observations of a Dynamic Event in the Solar Corona     

Innes  D. E.  Curdt  W.  Dwivedi  B. N.  Wilhelm  K. 《Solar physics》1998,181(1):103-112

The Solar Ultraviolet Measurements of Emitted Radiation instrument (SUMER) observations show high Doppler shifts and temporal variations in profiles of ultraviolet lines from low temperature gas in the corona above the active region NOAA 7974. The profiles indicate 100 km s^-1 flows coming from an almost stationary source that appears bright in the lines of N III and Si III. The variations in line-of-sight velocities and intensities suggest small knots of cooling plasma emanating from a small region high in the corona. A few arc sec sunward of the region where the cool flows are seen is an elongated region of enhanced higher temperature, low velocity Ne VI and Mg VI line emission.  相似文献   

Biogeochemical Evolution of Domestic Waste Water in Septic Systems: 2. Application of Conceptual Model in Sandy Aquifers   总被引：3，自引：0，他引：3  

Sheryl R. Wilhelm  Sherry L. Schiff  William D. Robertson 《Ground water》1996,34(5):853-864

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A sediment core sectioning method to minimize the post-sampling redistribution of organisms     

Frank M. Wilhelm  David C. Lasenby 《Aquatic Sciences - Research Across Boundaries》1997,59(1):34-38

We present a mechanical method to horizontally section soft bottom sediment cores to minimize the vertical post-sampling redistribution of motile infaunal macroinvertebrates. A clear acrylic core tube for a standard Kajak-Brinkhurst corer was modified by cutting a series of horizontal slits into the side of the core tube to allow the insertion of sectioning plates for physically sealing each section immediately after core retrieval. The modification is simple, inexpensive and easily adapted to any open barrel gravity corer.  相似文献   

Opening address     

E. Wilhelm  Co-Chairman 《Journal of Geochemical Exploration》1989,32(1-3)

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Experimental investigation of the kinetics of the reaction 1 tremolite+11 dolomite⇌8 forsterite+13 calcite+9 CO2+1 H2O     

Wilhelm Heinrich  Paul Metz  Matthias Gottschalk 《Contributions to Mineralogy and Petrology》1989,102(2):163-173

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Melting and subsolidus reactions in the system K2O-CaO-Al2O3-SiO2-H2O: corrections and additional experimental data   总被引：2，自引：0，他引：2  

Manfred Schliestedt  Wilhelm Johannes 《Contributions to Mineralogy and Petrology》1984,88(4):403-405

Melting relationships in the system K₂O-CaO-Al₂O₃-SiO₂-H₂O have been reinvestigated using Schreinemakers analysis and hydrothermal experiments. The reaction sanidine+muscovite+zoisite+quartz+vapor =melt has been bracketed at 10, 15, and 20 kbars and 670–680, 680–690, and 690–700° C, respectively and it marks the lowest solidus temperatures in the system investigated.Below 10 kbars, experimental data on the beginning of melting in zoisite- or muscovite-bearing anorthite+sanidine assemblages have been obtained, which are not showing any differences and therefore point to melt compositions close to the feldspar-quartz join.  相似文献   

A new relation between the central spectral solar H I Lyman α irradiance and the line irradiance measured by SUMER/SOHO during the cycle 23     

Claude Emerich  Philippe Lemaire  Werner Curdt  Klaus Wilhelm 《Icarus》2005,178(2):429-433

The spectral irradiance at the center of the solar H I Lyman α (, referred to as Lyα in this paper) line profile is the main excitation source responsible for the atomic hydrogen resonant scattering of cool material in our Solar System. It has therefore to be known with the best possible accuracy in order to model the various Lyα emissions taking place in planetary, cometary, and interplanetary environments. Since the only permanently monitored solar irradiance is the total one (i.e. integrated over the whole Lyα line profile), Vidal-Madjar [1975. Evolution of the solar Lyman alpha flux during four consecutive years. Solar Phys. 40, 69-86] using Orbiting Solar Observatory 5 (OSO-5) satellite Lyα data, established a semi-empirical formula allowing him to deduce the central spectral Lyα irradiance from the total one. This relation has been extensively used for three decades. But, at the low altitude of the OSO-5 orbit, the central part of the solar line profile was deeply absorbed by a large column of exospheric atomic hydrogen. Consequently, the spectral irradiance at the center of the line was obtained by a complex procedure confronting the observations with simulations of both the geocoronal absorption and the self-reversed shape of the solar Lyα profile. The SUMER spectrometer onboard SOHO positioned well outside the hydrogen geocorona, provided full-Sun Lyα profiles, not affected by such an absorption [Lemaire et al., 1998. Solar H I Lyman α full disk profile obtained with the SUMER/SOHO spectrometer. Astron. Astrophys. 334, 1095-1098; 2002. Variation of the full Sun Hydrogen Lyman α and β profiles with the activity cycle. Proc. SOHO 11 Symposium, ESA SP-508, 219-222; 2004. Variation of the full Sun Hydrogen Lyman profiles through solar cycle 23. COSPAR 2004 Meeting], making it—for the first time—possible to measure the spectral and total Lyα solar irradiances directly and simultaneously. A new relation between these two quantities is derived in an expression that is formally similar to the previous one, but with significantly different parameters. After having discussed the potential causes for such differences, it is suggested that the new relation should replace the old one for any future modeling of the numerous Lyα absorptions and emissions observed in the Solar System.  相似文献   

Eutrophication processes and trophic interactions in a shallow estuary: Preliminary results based on stable isotope analysis (δ13C and δ15N)     

Paulo Cesar Abreu  César S. B. Costa  Carlos Bemvenuti  Clarisse Odebrecht  Wilhelm Graneli  Alexandre M. Anesio 《Estuaries and Coasts》2006,29(2):277-285

Stable isotopes ratios (δ¹³C and δ¹⁵N) were measured in primary producers and consumers of two bays with contrasting eutrophic conditions in the Patos Lagoon estuary, southern Brazil: the Justino bay, a more pristine ecosystem, and the Mangueira bay, a heavily polluted region that receives the Rio Grande city sewage and effluencts of several industries. δ¹³C values of organisms collected in both subsystems were not different, but δ¹⁵N values had significant statistical differences, ca. 3.5‰ higher in the Mangueira bay. It is likely that primary producers and consumers in this subsystem are greatly influenced by higher nitrogen input due to domestic and industrial sewages. The stable isotope analysis also corroborated several trophic interactions previously established by gut content analysis, and due to its higher sensitivity, it was possible to better determine the contributions of different primary producers and detrital fractions to the consumers' diets. It was confirmed that plant detritus represents the main food source for most organisms. The stable isotope analysis also demonstrated that detritivorous benthic organisms in the same habitat have distinct diet compositions, with differential consumption of C3 and C4 plants. This technique showed that some consumers that eat detritus do not have in their stable isotopic signature any relationship with that of plants. It is likely that these consumers assimilate their carbon and nitrogen from other sources like microalgae or microorganisms that colonize decaying plants.  相似文献